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CAS - 55566 - 30 - 8
Tetrakis (Hydroxymethyl) Phosphonium Sulfate (THPS) 75%
CAS - 55566 - 30 - 8
Application
It is highly critical for upstream production and midstream transport because it solves two major oilfield threats simultaneously: microbial corrosion and pyrophoric iron scale.
- Control of Sulfate-Reducing Bacteria (SRB)
The downhole environment is a prime breeding ground for harmful anaerobic bacteria, specifically Sulfate-Reducing Bacteria (SRB).
- The Threat: SRB metabolize sulfates in injection water and produce highly toxic, corrosive Hydrogen Sulfide gas (Hâ‚‚S), which sours the reservoir and causes rapidly accelerating pitting corrosion in steel pipelines.
- THPS Role: At 75% concentration, THPS penetrates the protective cellular biofilms of bacteria. It disrupts their cell membranes and metabolic enzymes, killing both free-floating and surface-attached bacteria.
- Dissolution of Iron Sulfide (FeS) Scale
When Hâ‚‚S gas reacts with steel equipment, it creates Iron Sulfide (FeS) scale. This scale clogs pipelines, plugs injection wells, and presents a severe safety hazard because it is pyrophoric (spontaneously ignites when exposed to air during maintenance).
- The Mechanism: THPS acts as a specialized chelating ligand. It chemically binds to the iron molecules inside the solid scale.
- The Result: It converts the insoluble, hard iron sulfide scale into a highly soluble, stable aqueous complex, cleanly dissolving the blockages without producing the hazardous Hâ‚‚S gas releases that occur when using hydrochloric acid.
- Protection of Hydraulic Fracturing Fluids
Hydraulic fracturing involves pumping millions of gallons of water containing organic polymers (like guar gum) downhole to open rock fractures.
- Polymer Protection: Bacteria naturally present in fracturing water will rapidly consume these organic polymers, destroying the fluid’s viscosity before it can transport proppant (sand) into the fractures.
- THPS Role: It is mixed into the slickwater or gel frac-fluid at the surface to sterilize the water instantly, ensuring the polymers remain intact until the job is completed.
- Water Injection System and Pipeline Maintenance
Produced water and seawater injected back into reservoirs must be kept sterile to prevent “reservoir souring.”
- Application: THPS 75% is applied via continuous injection or high-concentration periodic “slug doses” into water injection lines and transport pipelines.
- Benefit: Because it is a non-foaming biocide, it can be safely pumped through pipelines without creating air pockets or disrupting downstream oil-water separators.
Key Operational Advantages
- Excellent Environmental Profile: Unlike older biocides like glutaraldehyde or acrolein, THPS breaks down rapidly into harmless substances (primarily oxygenated phosphorus compounds) in the environment, making it favored for offshore drilling.
- High Thermal Stability: It remains chemically active and stable in high-temperature downhole reservoirs up to 140°C.
- Low Toxicity to Operators: It has a significantly lower vapor pressure than aldehyde-based biocides, drastically reducing toxic fumes for field workers handling the chemical at the surface
Packaging: Our Tetrakis (hydroxymethyl) Phosphonium Sulfate (THPS) 75% is supplied in 265 USG per IBC Tote
Contact Us
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868-225-4857 / 4858
Please contact Jessica Mohammed
jmohammed@greensolltd.com
Address
GreenSol Ltd, Building 2, Unit 3,
61-67 Cipero Road, Retrench Village, San Fernando,
Trinidad, West Indies
Operations & Warehousing: 14 Union Village, Couva, Trinidad, West Indies (All Sample Deliveries)

